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You want to stop automatic syncing function and sync actively by yourself? Then these following steps will show you how to:
1. Open iTunes
2. Tap on iPhone to select it in the sidebar
3. Choose Sync in the bottom-right corner of the screen, or if you have already made any changes in Sync settings then click Apply to finish it.
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Later on, you can sync actively by yourself without being annoyed by automatic sync function of iPhone.
Read: iPhone 4: How to Sync Manually