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Check out how you can stop the iPhone function of automatic syncing for one time, without changing the original settings.
1. Activate iTunes.
2. Connect iPhone to your PC.
3. Press and hold Command-Option (if you are using a Mac) or Shift-Control (if you are using a PC) until iPhone icon appears in the sidebar.
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Now you can prevent iPhone from automatic syncing for this time without making any changes to your original settings on the iPhone 4.
Read: iPhone 4: How to Prevent Automatic Syncing One Time, Without Changing Settings